Electrochemical studies, mainly cyclic voltammetry, square wave voltammetry and chronoamperometry, were carried out to study the behavior of dissolved silicon species in molten LiF-KF with additions of K2SiF6 at temperatures from 550 to 800 °C. Electrolysis experiments were run at constant current...
Choline Chloride-Ethylene Glycol DES mixture (ethaline) is considered a green solvent and is one of the most popular DESs to combine with electrochemical recovery processes due to its superior electrochemical properties compared to other DES systems. In this work, electrochemical behaviour of...
Grande, SINTEF WALID - Fremtidens materialer i vindmøller v/ Kjetil Larsen, Norner REE4EU - Recycling of Rare Earth Materials in pilot scale v/ Ana Maria Martinez/SINTEFog Kjell Blandhol, Elkem SecREEts - Game-changing rare earth elements extraction project v/ Stian Nygaard, Yara Biprodukt fra smelteverk...
The electrochemical de-oxidation process, also called FFC-Cambridge process, has been proposed previously to produce reactive metals and their alloys through reduction of their metal oxides. The process works by introducing metal oxides into a molten salt bath where it is electrolysed to form metal...
Recycling of electronic waste to recover the metal value is of prime importance, especially for metals with limited resources. An electrochemical approach should be an interesting option to develop sustainable recycling processes. The electrochemical deposition of tin was studied by cyclic...
Anode gas bubble behavior and anode effect on graphite and industrial carbon rod-shaped anode in a cryolite melt have been studied using a see-through furnace. The different carbon materials have different properties which can affect bubble behavior and electrochemical properties. Industrial carbon...
The anode potential has been shown to be highly dependent on anode geometry and orientation in the Hall–Héroult process. This work is an experimental laboratory scale study of the effect of anode geometry and orientation on bubble formation and detachment for four different anode designs: horizontal...
The use of molten salts as “solvents” offers interesting possibilities for the treatment of ores, industrial by-products as well as scraps, allowing the development of processes that are mid-way between pyro- and hydrometallurgy, with the advantage of salts offering a wide choice of chemical and...
A new kind of membrane free liquid metal battery was developed. The battery employs liquid sodium and zinc as electrodes both in liquid state, and NaCl-CaCl2 molten salts as electrolyte. The discharge flat voltage is in the range of about 1.4 V–1.8 V, and the cycle efficiency achieved is about...
...grunnstoffene har vokst mye raskere enn produksjonen. Ifølge prognoser blir det knapphet på flere av dem allerede fra 2015. TEKNOLOGIEN: SINTEFs Ana Maria Martinez forbereder et gjenvinnings-eksperiment. En prøveholder med magnetmateriale skal inn i en forsøksovn for høytemperatur elektrolyse. Der venter...
Molten Oxide Electrolysis (MOE) is a new CO2-free technology that could alleviate the environmental impact of ferroalloy production. In this work the objectives were to perform (i) experimental lab scale studies of MOE for Mn from MnO using synthetic raw materials and a commercial Ni–Cr–Fe alloy as...
Iron metal is traditionally produced by carbothermic reduction in a blast furnace; an effective, but capital and energy intensive method that produces large amounts of CO2, SO2 and a variety of other contaminating byproducts. An alternative route to produce iron might be electrolysis in aqueous...
Gas bubble behavior on a carbon anode in a cryolite melt has been studied using a see-through cell. The phenomena studied have been growth, coalescence, detachment, and wetting during electrolysis. The surface orientation affects bubble behavior. Therefore, two different anode designs were tested...
Tungsten is a basic metal commodity that is classified as critical raw material (CRM) by the European Commission (EC) with the highest economical importance compared to other CRM. Thanks to its unique properties, secure W supply is critical to all industrial applications involving cutting or...
One of the main applications of REs by value is in permanent magnets, especially those magnets based on neodymium alloys. This is mainly due to the growing use of electrical and hybrid-electrical vehicles. Then the increase of waste streams (end-of-life products and manufacturing scrap) related...
One of the most important sources of renewable energy is solar energy, and the estimated future growth in this sector will require large amounts of materials. Solar panels have a life span of 25–30 years, and developing recycling processes to recover the strategic materials is critical considering...
PLATInum group metals Recovery Using Secondary raw materials (PLATIRUS), a European Union (EU) Horizon 2020 project, aims to address the platinum group metal (pgm) supply security within Europe by developing novel and greener pgm recycling processes for autocatalysts, mining and electronic wastes...
...miljø er gode grunner til å rette søkelyset mot utvinningsmuligheter vi har på europeisk jord, sier seniorforsker i SINTEF Ana Maria Martinez. Gjenvinne framfor utvinne Martinez har ledet en rekke prosjekt for å etablere gode løsninger for resirkulering og utvinning av de kritiske råmaterialene. Vi spurte...
The recent exponential growth in the Li ion batteries (LIB) market, is largely driven by the demand for electric vehicles and the general transition to a green and digital economy. It is therefore imperative to develop more effective and economic processes for recovering battery raw materials such...
SINTEF Lisbeth Alnæs, seniorforsker SINTEF Ana Maria Martinez, sjefforsker SINTEF Kl. 10.40 DEL 1 Harde fakta (behovene, lovverket, statistikken) Innlegg og diskusjon rundt bordene <!-- [if !supportLists]-->Mineralbehov og utfordringer, Ana Maria Martinez, sjefforsker SINTEF Bærekraft, natur og...