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Generation and Structural Characterization of a Gold(III) Alkene Complex

Generation and Structural Characterization of a Gold(III) Alkene Complex

Kategori
Vitenskapelig artikkel
Sammendrag
A Missing Gold Link: An AuIII alkene complex has been prepared and characterized by NMR spectroscopy and X-ray crystallography. Its bonding features have been analyzed by DFT calculations and natural bond orbital (NBO) analysis. In [(cod)AuMe2]+, the unequal AuC bond lengths result from the domination of the preference of 1,5-cyclooctadiene (cod) for nonparallel double bonds over back donation from the metal which favors parallel double bonds.
Oppdragsgiver
  • Research Council of Norway (RCN) / 179568
  • Notur/NorStore / nn4683k
  • Research Council of Norway (RCN) / 185513
  • Notur/NorStore / NN4683K
Språk
Engelsk
Forfatter(e)
  • Eirin Langseth
  • Margaret Louise Scheuermann
  • David Balcells
  • Werner Kaminsky
  • Karen I. Goldberg
  • Odile Eisenstein
  • Richard H Heyn
  • Mats Tilset
Institusjon(er)
  • Universitetet i Oslo
  • University of Washington
  • Université de Montpellier I
  • SINTEF Industri / Materialer og nanoteknologi
År
Publisert i
Angewandte Chemie International Edition
ISSN
1433-7851
Forlag
Wiley-VCH
Årgang
52
Hefte nr.
6
Side(r)
1660 - 1663