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A highly asymmetric gold(III) η3‐allyl complex

A highly asymmetric gold(III) η3‐allyl complex

Category
Journal publication
Abstract
A highly asymmetric AuIII η3‐allyl complex has been generated by treating Au(η1‐allyl)Br(tpy) (tpy=2‐(p‐tolyl)pyridine) with AgNTf2. The resulting η3‐allyl complex has been characterized by NMR spectroscopy and X‐ray crystallography. DFT calculations and variable temperature 1H NMR suggest that the allyl ligand is highly fluxional.
Client
  • Norges forskningsråd / 250044
  • Norges forskningsråd / 226244
  • Norges forskningsråd / 221801
  • Norges forskningsråd / 262695
  • Norges forskningsråd / 185513
Language
English
Author(s)
  • Holmsen Marte Sofie
  • Nova Ainara
  • Øien-Ødegaard Sigurd
  • Heyn Richard H.
  • Tilset Mats
Affiliation
  • University of Oslo
  • University of Oslo
  • UiT The Arctic University of Norway
  • SINTEF Industry / Process Technology
Year
2019
Published in
Angewandte Chemie International Edition
ISSN
1433-7851
Publisher
Wiley - VCH Verlag GmbH
Volume
59
Issue
4
Page(s)
1516 - 1520