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Closing of micro-cavities in well cement upon exposure to CO2 brine


Long-lasting cement plugging of wells is crucial for successful CO2 storage in underground reservoirs. It requires a profoundly improved understanding of the behavior of fractured cement under realistic subsurface conditions including elevated temperature, high pressure and the presence of CO2 saturated brine. Here we report computed X-ray tomography studies on the effects of CO2 on cement. More specifically, we have exposed cured Portland G cement samples with pre-made microchannels mimicking fractures to CO2 saturated brine at elevated pressure (100 bars) and room temperature. The microchannels were observed to get filled with calcite (CaCO3) during the CO2 exposure. The extent of this self-healing was dependent on the diameter of the leakage path, with narrower channels more readily getting clogged. Chemical simulations taking into account the cement composition, CO2 availability, pH, pressure and temperature gave results consistent with our conceptual understanding of how the differences in dissolution/precipitation profiles in the cement may result from the availability of CO2. In particular, the modelling provides an explanation why calcite precipitates preferentially in the channels rather than on the external cement sample surfaces. We conclude that the localized precipitation can be ascribed to higher pH inside the cavities compared to near the external surfaces, owing to long diffusion distances giving a locally limited CO2 supply within the voids.


Academic lecture


  • Research Council of Norway (RCN) / 193816
  • Research Council of Norway (RCN) / 243765




  • Elvia Anabela Chavez Panduro
  • Malin Torsæter
  • Kamila Maria Gawel
  • Ruben Bjørge
  • Gibaud Alain
  • Yang Yi
  • Sørensen Henning
  • Peter Frykman
  • Claus Kjøller
  • Dag Werner Breiby


  • Unknown
  • Norwegian University of Science and Technology
  • SINTEF Industry / Petroleum
  • SINTEF Industry
  • Le Mans University
  • University of Copenhagen
  • The Geological Survey of Denmark and Greenland

Presented at

13th International Conference on Greenhouse Gas Control Technologies




14.11.2016 - 18.11.2016



View this publication at Cristin