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Dislocation formation in seeds for quasi-monocrystalline silicon for solar cells

Abstract

An investigation of two industrially cast quasi-monocrystalline silicon blocks revealed a high dislocation density originating at intersections between the seed crystals. This may be ascribed to three different generation mechanisms. Firstly, a dislocation cell structure was observed in the seed crystals, probably as an effect of poor surface preparation of the seeds. Furthermore, clusters of dislocations form around contact points in the interface between two neighbouring seeds. At contact points, the two monocrystalline silicon seeds plastically deform and sinter together. Dislocation rosettes form as a result of an indentation mechanism at high temperatures. A third mechanism acts at the bottom surface, where dislocation clusters also form by indentation of contact points between the seed and the crucible. Since dislocations forming in the seeds will continue into the growing ingot, it is crucial to depress the dislocation formation in the seeds.

Category

Academic article

Language

English

Author(s)

  • Torunn Kringlen Ervik
  • Gaute Stokkan
  • Tonio Buonassisi
  • Øyvind Mjøs
  • Otto Lohne

Affiliation

  • Norwegian University of Science and Technology
  • SINTEF Industry / Sustainable Energy Technology
  • Massachusetts Institute of Technology (MIT)
  • Singapore

Year

2014

Published in

Acta Materialia

ISSN

1359-6454

Publisher

Pergamon Press

Volume

67

Page(s)

199 - 206

View this publication at Cristin