Abstract
Cement nanocomposites with carbon nanofibers (CNFs) are electrically conductive
and sensitive to mechanical loads. These features make them useful for sensing applications.
The conductive and load sensing properties are well known to be dependent on carbon nanofiber
content; however, much less is known about how the conductivity of hybrid cement–CNF depend on
other parameters (e.g., water to cement ratio (w/c), water saturation of pore spaces and temperatures
above ambient temperature). In this paper we fill-in these knowledge gaps by: (1) determining a
relationship between the cement–CNF bulk resistivity and w/c ratio; (2) determining the effect of
water present in the pores on bulk resistivity; (3) describing the resistivity changes upon temperature
changes up to 180 ◦C. Our results show that the increase in the water to cement ratio results in
increased bulk resistivity. The decrease in nanocomposite resistivity upon a stepwise temperature
increase up to 180 ◦C was found to be related to free water release from cement pores and the dry
materials were relatively insensitive to temperature changes. The re-saturation of pores with water
was not reversible with respect to electrical resistivity. The results also suggest that the change in the
type of electrical connection can lead to two orders of magnitude different bulk resistivity results for
the same material. It is expected that the findings from this paper will contribute to application of
cement–CNF-based sensors at temperatures higher than ambient temperature
and sensitive to mechanical loads. These features make them useful for sensing applications.
The conductive and load sensing properties are well known to be dependent on carbon nanofiber
content; however, much less is known about how the conductivity of hybrid cement–CNF depend on
other parameters (e.g., water to cement ratio (w/c), water saturation of pore spaces and temperatures
above ambient temperature). In this paper we fill-in these knowledge gaps by: (1) determining a
relationship between the cement–CNF bulk resistivity and w/c ratio; (2) determining the effect of
water present in the pores on bulk resistivity; (3) describing the resistivity changes upon temperature
changes up to 180 ◦C. Our results show that the increase in the water to cement ratio results in
increased bulk resistivity. The decrease in nanocomposite resistivity upon a stepwise temperature
increase up to 180 ◦C was found to be related to free water release from cement pores and the dry
materials were relatively insensitive to temperature changes. The re-saturation of pores with water
was not reversible with respect to electrical resistivity. The results also suggest that the change in the
type of electrical connection can lead to two orders of magnitude different bulk resistivity results for
the same material. It is expected that the findings from this paper will contribute to application of
cement–CNF-based sensors at temperatures higher than ambient temperature