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Oxidation of Cellulose

Abstract

Oxidation ageing experiments on paper and transformer oil insulation has been performed using two different techniques. First, we used oxygen pressurized bottles with oil-paper isolation where oil and paper are sampled at certain intervals during 8 months and degree of polymerization is measured. Second, a microcalorimeter measuring continuously the heat flow from the paper-oil sample was used. We find that the degradation reaction rate is not linear with oxygen concentration and that the activation energy of oxidation is different from what has earlier been found for hydrolysis. The microcalorimeter seems to mimic ageing characteristics for oxidation and can potentially be a useful tool for quick ageing investigations.

Category

Academic chapter

Language

English

Affiliation

  • SINTEF Energy Research / Electric Power Technology
  • Norwegian University of Science and Technology

Year

2008

Publisher

IEEE (Institute of Electrical and Electronics Engineers)

Book

Conference record of the 2008 IEEE International Symposium on Electrical Insulation

ISBN

9781424420919

View this publication at Norwegian Research Information Repository