CO2 capture and transport-conditioning through liquefaction (Task 4)

The task is looking to use liquefaction to optimise the transport condition of CO2, thus making liquification a mandatory processing stage in the interface between capture and transport. To do this, an efficient CO2 liquefier process will be derived. Important criteria are energy- and cost efficiency adhering to transport specifications and safety.

As describes in CO2 value chain and legal aspects (Task 1) , CO2 transport is an important piece of the value CCS value chain. We are looking to use liquefaction to optimise the transport condition of CO2. To do this, we need to derive an efficient CO2 liquefier process designs.

As described in Task 1, shipping of CO2 is most likely to be the preferred mean of transport. Hence, liquefaction will be a mandatory processing stage in the interface between capture and transport, thus playing an imperative role in the CSS value chain. Important design criteria are therefore energy- and cost efficiency adhering to transport specifications, and safety.

As a proof of concept, a pilot rig for CO2 liquefaction with 10–15 t CO2/day capacity is under commissioning, financed under the ECCSEL programme.

Through its research, the this task will provide other tasks with important insight like:

Several of our activities, such as process modelling and simulation, is of relevance to potential suppliers of post-, oxy- and pre-combustion capture units, as well as critical components thereof. Further, it is also of general relevance to shipping companies that are potential shippers of liquid CO2 between the points of capture and unloading.

Results 2018

Main Results

  • Due to extremely high activity on commissioning the laboratory pilot facility, we have asked for very low budgets so far, with the aim of expanding on experimental activity beyond 2018
  • Other work ongoing until the end of 2018 (comparison of two different processing routes for CO2 liquefaction), not concluded at the time of reporting. KPIs to be compared comprise: Specific energy usage, total swept compressor volume, CO2 purity, CO2 recovery and more.

Impact and innovations

  • In parallel with NCCS, but with high relevance to potential future NCCS work, we have successfully commissioned the 10 t/d CO2 liquefaction pilot plant and run several tests for separation of N2 and CO2. This infrastructure can be very useful for NCCS in the coming years.
Interior of the 10 t/d CO2 liquefaction and separation pilot facility

Results 2017

The main activity was to provide an overview of the relevant inlet and outlet boundary conditions and specifications (compositions, temperature, pressure etc.) to which CO2 liquefaction processes must adhere. The gathering of information was done by data collection from other deliverables where available, as well as by communication with other NCCS tasks.

Examples of inlet boundary specifications are: CO2 captured from post-combustion capture with relatively high purity, and CO2-enriched synthesis gas retentate from protonic membrane reforming (PMR). Outlet specifications are mainly high-pressure CO2 for pipeline transport and liquid CO2 for ship transport. Low-temperature CO2 processing and its adherence to the various boundary conditions in post- and pre-combustion applications was given an initial consideration.

In parallel with the NCCS work, the task core group is involved in the construction and commissioning of a laboratory pilot infrastructure for low-temperature CO2 separation and liquefaction, funded through the ECCSEL infrastructure programme. The infrastructure has a capacity in the range 5–15 ton CO2 per day, and can operate down to around -55°C temperature range and up to 120 bar pressure. Upon completion, the infrastructure will be available for experimental activities relevant for NCCS.

Task leader

David Berstad

Research Scientist
Name
David Berstad
Title
Research Scientist
Phone
930 02 784
Department
Gas Technology
Office
Trondheim
Company
SINTEF Energi AS